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book review
"Rapid Spot Testing of Metals, Alloys and Coatings" by Andrew Holmes
Reviewed by John Gustav Delly, Scientific Advisor
Rapid
Spot Testing of Metals, Alloys and Coatings
by Andrew Holmes
Co-published by Metal Finishing Information Services Ltd.,
P.O. Box 70
Stevenage, Herts, SG1 4DF, UK
and ASM International, Materials Park,
Ohio 44073-0002 USA
ISBN: 0-904477-25-8
23.5 cm X 15.5 cm.
210 pages, Illustrated, Soft Cover. $120 ($96 for ASM members).
The colorful illustrations
on the front cover of this book summarize a few of the physical and chemical
methods that enable one to identify or distinguish metals and alloys,
and determine their composition on a semi-quantitative basis, especially
when in the field, or where there is no laboratory equipped with high-cost
instrumentation. The front-cover illustrations depict microchemical spot
tests, flame tests, and spark tests.
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click image to enlarge (251K)  |
All of
the tests described only take a minute or two to perform. In addition
to a large range of chemical spot tests using both simple acids and more
complex organic reagents, flame tests, and use of a grinding wheel to
study the color and form of the sparks emitted, the tests include density,
color, magnetic properties, and electrography. Flow charts and logic schemes
guide users through test sequences. Appendices describe the reagents used,
and list sources of further information and supplies.
More specifically,
the genesis of this book stems from an article published in 1999 on spot
tests for the metal finisher, which appeared in metal finishing trade
publications. In preparing the article, the author noticed how scattered
and, in some cases, obscure the published sources of information were
- microscopists and microchemists who value these kinds of tests are already
aware of this situation. He also found that many of the original sources
of useful tests were out of print - again, microscopists and microchemists
share this observation. These were sufficient reasons to persuade the
author to compile this text.
Chapter 1, Getting
Started, introduces the reader to spot testing - where they apply, equipment
needed, glassware, commercial kits.Chapter 2 is devoted to Identifying
Metals by Physical and Inorganic Chemical Spot Testing, and includes discussions
of cleaning, color, density, magnetism, sparking, drilling, fractures,
passivates and non-metallic surface coatings, solubility in acids, initial
chemical testing, mercury droplets and salt solutions, systematic scheme
for analysis and flame testing. A list of references concludes the chapter.
Chapter 3 is devoted
entirely to identifications using organic reagents. Chapter 4 discusses
Differentiation of Alloy Groupings. This is a very useful chapter for
home shop machinists as well, because it describes rapid ways of differentiating
aluminum and its alloys, high-magnesium alloys, nickel alloys, copper-containing
alloys, titanium alloys, and, of course, the various steels.
Chapter 5 describes
the Identification of Metals by Electrography. This is a relatively simple,
and very valuable method that is not commonly known by microscopists.
I strongly recommend reading W.S. Berl's contribution on the subject as
it appears in Volume 2 (pp. 155-218) of Physical Methods in Chemical
Analysis (Academic Press, 1951).
A brief Final Word,
Chapter 6, is followed by several appendices: Appendix 1 lists the reagents
used in the book, and describes how to make them up; Appendix 2 is a list
of the potential series of the elements; Appendix 3a is a list of the
SAE codes for steel compositions; Appendix 3b is a list of steel alloy
characteristics; Appendix 4a lists examples of color codes for wrought
aluminum mill products (U.S. Aluminum Association); Appendix 4b lists
the numbers of major alloying elements of aluminum alloys; Appendix 4c
lists temper designations of aluminum alloys. The last appendix lists
sources of information.
Microchemical tests
have been used for about 200 years now, and they are just as useful today
as they have been throughout the last two centuries. I, for one, am delighted
to welcome this new offering to the books on rapid spot testing of metals
and alloys, and look forward to recommending this text when I prepare
my updated, continuing, on-line version of the literature of microchemistry
for the microscopist [The Microchemical Bench: Part 6. The Literature
of Classical Microchemistry, The Microscope 47:1, pp. 13-28 (1999)].
I just wish this book was offered in hardcover. I will, of course, have
my copy hardbound, because a book such as this will be used frequently.
Microscopists and microchemists will find this book a useful addition
to their spot-tests library, but it will also be of value to scrap-metal
handlers, those with home shops, trade schools; indeed, for anyone handling
or dealing with metals of unknown composition and provenance.
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