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The Literature of Classical Microchemistry, Spot Tests, and Chemical Microscopy
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John Gustav Delly, Scientific Advisor, College of Microscopy, Westmont, IL |
THEODORE G. WORMLEY
As already mentioned, in 1915 É.M. Chamot stated that
"...the earliest comprehensive work dealing with microchemical methods was
from the pen of an American –Theodore G. Wormley."
Theodore Wormley, M.D. (Figure 7) was Professor of Chemistry
and Toxicology in the Starling Medical College, and of Natural Sciences in
Capital University, Columbus, Ohio. In 1857, he announced his intention to
publish a book on the microchemistry of poisons, and a prospectus announcing
its plan was published in March, 1861, at which time the drawings were almost
completed. A
few years afterward (1865), A. Helwig published his Das Mikroskop in der
Toxikologie [Helwig, A. (1865)], but
it would prove to be nowhere near the magnitude of Wormley's book. The first
edition of Wormley's Micro-chemistry of Poisons [Wormley, Theodore G.,
M.D. (1867)], was
published in 1867. In his Introduction, Wormley defines what he means by
microchemistry: "By the term MICRO-CHEMISTRY
of POISONS, we understand the study of the chemical properties of
poisons as revealed by the aid of the microscope." In the Preface, he
states, prophetically, "Heretofore the microscope has received but little
attention as an aid to chemical investigations, yet it is destined to very
greatly expand our knowledge in this department of study." His superb
book is quite large (668 pages), and contains seventy-eight illustrations
engraved upon steel. Interestingly, Wormley could not find an engraver who
would take on the task of engraving the microscopical images of the delicate
crystalline reactions, so his wife taught herself to engrave in steel, and
it was she who drew from nature and transferred to steel all of the microscopical
images in the form of thirteen beautiful plates. Wormley affectionately
dedicated the book to her. In the back of the book, there is a long, fold-out
Tabular View of the Behavior of Alkaloids with Reagents. The described tests
and Wormley's book in general, are as valid and useful today as they were almost
140 years ago. Demand for the book was strong, and necessitated a second
edition [Wormely, Theodore G., M.D. (1885)], in 1885, by which time Wormley
was Professor of Chemistry and Toxicology in the Medical Department of the
University of Pennsylvania. This second edition is enlarged to 784 pages, with
ninety-six illustrations, an Appendix on the Detection and Microscopic Discrimination
of Blood, and a chromolithographic frontispiece of blood spectra. Additional
tests and case-histories were added, as well as a revision of the chemical
nomenclature. Wormley's book in either edition is
highly recommended, both for its historical significance and for its still
useful microchemical tests. It is found in both one and two-volume versions.
[Unfortunately, my copies are too
tightly bound to be scanned for illustrations without damage to the book.]
click image to enlarge (171K)
Figure
7. Theodore G. Wormley, M.D. Portrait in McCrone Research
Institute Museum. |
EMANUEL BORICKY
Emanuel Boricky was Professor Extraordinaire at the University of Prague, and Curator of the Bohemian Museum, in what is today the Czech Republic. In 1877, he published a very important contribution on the microchemical
analysis of rocks and minerals. The publication (Figure 8), Elements of a New Chemical Microscopical Analysis
of Minerals and Rocks [Boricky, Emanual
(1877)], constituted a part of the Chemical-Petrological
Division's Natural History Investigation of Bohemia. In it, he described the
removal of small samples of the mineral components of rocks, and their
subsequent microchemical analysis with the aid of the microscope. The
relatively short publication (80 pages) contains three woodcuts, and is also
illustrated with two lithographic plates showing the microscopical appearance
of the chemical reactions (Figure 9). An English translation [Winchell N.H.
(1892)], of this valuable monograph was published by Professor N.H. Winchell in
the Nineteenth Annual Report (1890) of the Geological and Natural History
Survey of Minnesota (Minneapolis, 1892).
The practical microscopist will not
have a need for this publication, which, like Raspail's works, are of
considerable interest, but they are essential items in the library of those
microscopists interested in the historical development of their craft.
click image to enlarge (234K)
Figure
8. Title page of Emanuel Boricky's monograph on Elements
of a New Chemical Microscopical Analysis of Minerals and Rocks (1877). |
click image to enlarge (225K)
Figure
9. One of two lithographic plates illustrating microchemical
reactions, from Boricky's 1877 monograph on the microchemical analysis
of minerals and rocks. |
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